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61.
Anwar M Bailey JH Dickinson LC Edwards HJ Goswami R Moloney MG 《Organic & biomolecular chemistry》2003,1(13):2364-2376
Alkylation reactions using alpha-halolactams or lactam enolates derived from bicyclic lactam templates can proceed with high endo- or exo- diastereoselectivity respectively. In the latter case, stereochemical correction by means of enolate generation and hindered phenol quench is possible with moderate efficiency. This protocol has been applied to the synthesis of protected penmacric acid and its analogues. 相似文献
62.
63.
A small change of one of the system parameters may not in general convert a bistable system to a monostable system. However, an external control in the form of a slow periodic parameter modulation can annihilate one of the coexisting states, and thus results in controlled monostability. The annihilation takes place because the state becomes chaotic via the period doubling route and the chaotic state undergoes boundary crisis within a small range of the control amplitude. These features are observed theoretically in two standard models, namely, Henon map and laser rate equations, and confirmed experimentally in a cavity loss modulated CO2 laser. 相似文献
64.
J. Rana G.L. Goswami S.K. Jha P.K. Mishra B.V.S.S.S. Prasad 《Optics & Laser Technology》2007,39(2):385-393
An experimental investigation with 5 kW CW CO2 laser system was carried out to study the effects of different laser and process parameters on the microstructure and hardness of carbon steel specimen with varying carbon percentage. The laser beam is allowed to scan on the surface of the work piece varying the power (1.1–2.5 kW) and traverse speed (6–15 mm/s) at two different spot sizes using TEM01* mode laser beam. The most hardenable microstructure achieved in case of three grades of carbon steel and the most influencing parameter on the value of hardness are reported. Besides the above study, some multipass operations are also carried out to recommend an appropriate gap between consecutive passes. 相似文献
65.
A lot of importance has been attached to the testing phase of the Software Development Life Cycle (SDLC). It is during this phase it is checked whether the software product meets user requirements or not. Any discrepancies that are identified are removed. But testing needs to be monitored to increase its effectiveness. Software Reliability Growth Models (SRGMs) that specify mathematical relationships between the failure phenomenon and time have proved useful. SRGMs that include factors that affect failure process are more realistic and useful. Software fault detection and removal during the testing phase of SDLC depend on how testing resources (test cases, manpower and time) are used and also on previously identified faults. With this motivation a Non-Homogeneous Poisson Process (NHPP) based SRGM is proposed in this paper which is flexible enough to describe various software failure/reliability curves. Both testing efforts and time dependent fault detection rate (FDR) are considered for software reliability modeling. The time lag between fault identification and removal has also been depicted. The applicability of our model is shown by validating it on software failure data sets obtained from different real software development projects. The comparisons with established models in terms of goodness of fit, the Akaike Information Criterion (AIC), Mean of Squared Errors (MSE), etc. have been presented. 相似文献
66.
We demonstrate coded self-assembly in nanostructures using the code seeded at the component level through computer simulations.
Defects or cavities occur in all natural assembly processes including crystallization and our simulations capture this essential
aspect under surface minimization constraints for self-assembly. Our bottom-up approach to nanostructures would provide a
new dimension towards nanofabrication and better understanding of defects and crystallization process.
相似文献
67.
68.
Here we investigate a majorization problem involving starlike function of complex order belonging to a certain class defined by means of fractional derivatives. Relevant connections of the main results obtained in this paper with those given by earlier workers on the subject are also pointed out. 相似文献
69.
Background
Organic light emitting devices (OLED) are becoming important and characterisation of them, in terms of structure, charge distribution, and intermolecular interactions, is important. Tris(8-hydroxyquinolinato)-aluminium(III), known as Alq3, an organomettalic complex has become a reference material of great importance in OLED. It is important to elucidate the structural details of Alq3 in its various isomeric and solvated forms. Solid-state nuclear magnetic resonance (NMR) is a useful tool for this which can also complement the information obtained with X-ray diffraction studies. 相似文献70.
B. S. Tomar A. Goswami S. K. Das T. Datta B. K. Srivastava A. G. C. Nair Satya Prakash M. V. Ramaniah 《Zeitschrift für Physik A Hadrons and Nuclei》1987,327(2):225-229
Independent isomeric yield ratios of128Sb were determined radiochemically in the thermal neutron induced fission of241Pu and 34 MeV alpha particle induced fission of238U, both involving the same compound nucleus (242Pu). Fragment angular momenta estimated from the measured isomer ratios using the statistical model analysis showed significantly larger fragment angular momenta in the medium energy fissioning system compared to the low energy fissioning system. This has been attributed to the effect of higher excitation energy and angular momentum in the entrance channel leading to increased fragment temperature, moments of inertia and angular velocity. An attempt was made to calculate the fragment angular momentum in the medium energy fission using the Fermi gas model for the fissioning nucleus, taking into account the multichance fission, saddle shapes of the fissioning nuclei and the angular velocity components of the fissioning nuclei both along and orthogonal to the fission axis. The calculated angular momenta agree well with the experimental results. 相似文献